AtoFina Petrochemicals has been broadening its portfolio of polyolefins based on its proprietary metallocene catalyst technology. There are now two commercial grades of a new family of Finacene metallocene MDPE (medium- density PE). They are being produced at the one of the world’s largest Phillips-type slurry-loop reactors, which has an annual capacity of 900 million lb/yr.
The first, launched in early 2001, is a blown-film grade, M 3410 EP (previously known as ER2245). It has a density of 0.934 g/cc and MI of 0.9. It is being marketed as a 20-30% blend component in LLDPE films. It reportedly offers good clarity (10% haze, 60 gloss rating at 45 degrees) and improvements in both physical properties and processability over other mPE resins in LLDPE films. When extruded by itself into 1-mil film on an LLDPE line, it shows 35% higher puncture strength and 60% higher tear strength than standard MDPE film, AtoFina says. It is also finding use as a 20-30% blend component for downgauging LDPE films and as a majority component (up to 90%) in overwrap.
The second Finacene grade, also of 0.934 g/cc and 0.9 MI, is a blow moldable MDPE, BM359 SG, that boasts gloss comparable to PP for packaging personal-care products, cosmetics, and detergents. Because
of its flexibility, it can be used by itself to make squeeze bottles, or it can be coextruded with a rigid HDPE. Besides high gloss, (60-90 rating at 45 degrees), it boasts high ESCR (>1000 hr), and high drop impact
strength. Marketing manager Allan Potter hints that an injection blow molding grade of metallocene MDPE is also under development.